full2010.pdf - page 1350

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¦¼žš¸É 2 IR spectra °Š˜´ªÁ¦nŠž’·„·¦·¥µ (a) Cu:Zn(pentaen) [1:1] ¨³
(b) Cu:Co(pentaen) [1:1]
¦»žŸ¨„µ¦ª·‹´¥
‹µ„Ÿ¨„µ¦´ŠÁ‡¦µ³®r¡°¨·¥¼¦¸ÁšœÃ¢¤ÂÂ Ȋ µ¤µ¦™¦»žÅ—oªnµµ¦ž¦³„°Á·ŠŽo°œ °ŠÃ¨®³Ÿ¤„´
°¤¸œÄœ°´˜¦µnªœ 1:1 ץä¨ µ¤µ¦™Á¦nŠž’·„·¦·¥µ„µ¦Á„·—â¤Å—o—¸„ªnµ°´˜¦µnªœ 1:2 ×¥ Cu:Zn(pentaen) Á¦nŠ
ž’· „·¦·¥µ„µ¦Á„·—â¤Å—o—¸š¸É »— ¦°Š¨Š¤µ‡º° Cu:Co(pentaen) ¨³ Cu:Ni(pentaen) ˜µ¤¨Îµ—´ Ž¹ÉŠ˜´ªÁ¦nŠž’·„·¦·¥µš´ÊŠ 3
œ·—µ¤µ¦™Á¦nŠž’·„·¦·¥µ„µ¦Á„·—¡°¨·¥¼¦¸ÁšœÃ¢¤Å—o—¸„ªnµÃ¢¤š¸Éčo˜´ªÁ¦nŠÁž}œž’·„·¦·¥µ°oµŠ°·ŠÄœ°»˜µ®„¦¦¤ (DMCHA)
o°—¸°Š˜´ªÁ¦nŠž’·„·¦·¥µÄœŠµœª·‹´¥œ¸Ê ‡º° ´ŠÁ‡¦µ³®rŗoŠn µ¥Â¨³Å¤n¤¸„¨·ÉœÁ®¤Èœ
‡Îµ °‡»–
Šµœª·‹´¥œ¸Êŗo ¦´‡ªµ¤°œ»Á‡¦µ³®r µ¦Á‡¤¸‹µ„¦·¬´š ÁŽµ˜r Ž·˜¸Ê ždئÁ‡¤ ‹Îµ„´— (South City Petrochem
Co., Ltd.)
Á°„µ¦°oµŠ°·Š
Inoue, S. I., Nagai, Y. and Okamoto, H. (2002). Amine-manganese complex as an efficient catalyst for polyurethane
Syntheses, Polym. J., 34, 298-301.
Kurnoskin, A. V. (1993). Metalliferous epoxy chelate polymers: 1. synthesis and properties, Polymer, 34,
1060-1067.
(a)
(b)
Wavenumber