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Fig.8. SEM micrographs of dynamically cured 60/40 DSNR/PP blend with various types of vulcanization systems.
Conclusion
Modification natural rubber with dibutyl phosphate were successfully performed, as proved by FTIR absorption
peaks at1030, 1069 and 1279 cm
-1
. It was also found that the highest degradation temperature(T
d
) was 393
o
C. In
addition, it was found that the dynamically cured 60/40 DSNR/PP blends with mixed sulphur-peroxide cured showed the
superior mechanical and dynamic properties and smallest rubber domians dispersed in the PP matrix.
Acknowledgment
We are grateful to Center of Excellence in Natural Rubber Technology (CoE-NR) and the government budget
with contract No. SAT5211990098a for financial support.
References
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Acetate Copolymer (EVA), with Natural Rubber-
graft
-Poly(dimethyl(methacryloyloxymethyl)phosphonate)
(NR-g-PDMMMP) as Compatibilizer. Ph.D. Thesis, Prince of Songkla University.
Charoen Nakason, Anuwat Worlee and Subhan Salaeh. (2008). Effect of vulcanization systems on properties and
recyclability of dynamically cured epoxided natural rubber/polypropylene blends. Polym. Test 27:858-869.
Derouet, D., Morvan, F. and Brosse, J.C. (2001). Chemical modification of 1,4-polydienes by di(alkyl or aryl)phosphates.
Eur. Polym. J. 37(7): 1297-1313.
Derouet, D., Brosse, J.C., Cauret, L., Morvan, F. and Mulder-Houdayer S. (2003). Chemical Modification of Polydienic
Elastomers by Organophosphorated Reagents., J. Appl. Polym. Sci 87: 47–60
Legge, N.R., Holden, G., Schroeder H.E. (Eds.) (1987). Thermoplastic Elastomer: A Comprehensive Review, Hanser
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Nakason, C., Wannavilai, P. and Kaesaman, A. (2006c).
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Peroxide system
Phenolic system
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