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µ¦ 1(0.0012ä¨) šÎµž’· „·¦·¥µ„´ CuI (0.0006 ä¨) š¸É°»–®£¼¤· 70 °Š«µÁŽ¨ÁŽ¸¥ Áž}œÁª¨µ 5 ´ÉªÃ¤ŠÅ—o
Ÿ¨·˜£´ –”rÁž}œŸ¨¹„¸Á ¸¥ª °Š Cu-1 Ž¹ÉŠ¤¸‹»—®¨°¤Á®¨ª 122.0-124.7 °Š«µÁŽ¨ÁŽ¸¥ IR (KBr, cm-1): 1586 cm-1,
1492(s) cm-1, 1415 cm-1. ‹³Á®Èœªnµ´µ–„µ¦´Éœ °Š C=O stretching °Š®¤¼nÁ°Å¤—rš¸É 1651 cm -1 ¨³´µ–„µ¦
´Éœ °Š N-H stretching š¸É 3267 cm-1Ĝµ¦ 1 ®µ¥Åž ˜n‹³¡´µ–„µ¦´Éœš¸É 1586 cm -1 Á¡·É¤ ¹Êœ
£µ¡š¸É 1 —ŠÃ‡¦Š¦oµŠÃ¤Á¨„» ¨Â¨³„µ¦‹´—Á¦¸¥Š˜´ª °ŠÃ¤Á¨„» ¨ Ĝ®œnª¥ÁŽ¨¨r‹µ„ X-ray diffraction
°Šµ¦ž¦³„°Á·ŠŽo°œ Cu-1
‹µ„ o°¤¼ ¨šµŠ X-ray diffraction ¡ªnµÃ‡¦Š¦o µŠŸ¨¹„ °Šµ¦ž¦³„°Á· ŠŽo°œ Cu-1 Áž}œÂ square
planar ץǦŠŸ¨¹„‹´ —°¥¼nĜ¦³ monoclinic ¤¸ÁŽ¨¨r¡µ¦µ¤·Á˜°¦r a = 10.5955(16), b = 18.3054(28), c =
13.4439(21)Å, E = 102.991(4)°, space group Áž}œ P21 /n ¨³¤¸¤ª¨Ã¤Á¨„» ¨Ášnµ„´ 534.25 Ž¹É ŠÁž}œ¨´„¬–³ °Šµ¦
Á·ŠŽo°œ °Š Cu(II) —Šªnµ Cu(I) ™¼ „°°„Ž·Å—rÁž}œ Cu(II)×¥¨· „œ—r ¨³ÄœÃ‡¦ŠŸ¨¹„Ťn¡Å°Ã°Å——r Ž¹ÉŠÅ—oŸ¨
ÁnœÁ—¸ ¥ª„´ Hermindez(2005)
2. Ÿ¨„µ¦´ ŠÁ‡¦µ³®r µ¦ž¦³„°Á·ŠŽo°œ Cu-2
µ¦ 2 (0.0007ä¨) šÎµž’·„·¦·¥µ„´ CuI (0.0006 ä¨) š¸É°»–®£¼¤· 70 °Š«µÁŽ¨ÁŽ¸¥ Áž}œÁª¨µ 5 ´ÉªÃ¤Š
ŗo Ÿ¨·˜£´–”rÁž}œŸ¨¹„¸¤¡¼Â¨³¸Á®¨º°Šžœ„´œ¥´ ŠÅ¤n µ¤µ¦™Â¥„Å—o¦· »š›·Í
Ÿ¨„µ¦š—°§š›·Í¥´¥´Ê ŠÁºÊ° Meliola sp.
Ÿ¨„µ¦¥´¥´ÊŠÁºÊ ° Meliola sp. °Š°œ» ¡´œ›rŚð¥¼Á¦¸¥Â¨³µ¦ž¦³„°Á·ŠŽo°œš¸É ´ŠÁ‡¦µ³®rŗo 3 ˜´ª°¥nµŠ
‡º° 1, Cu-1 ¨³ 2 —´ŠÂ—ŠÄœ˜µ¦µŠš¸É 1 ¨³£µ¡š¸É 2
˜µ¦µŠš¸É 1 —ŠÁž°¦rÁŽÈ œ˜r„µ¦¥´¥´ÊŠÁºÊ° Meliola sp. °Šµ¦ 1 ¨³ 2 ¨³Cu-1 š¸É‡ªµ¤Á o¤ oœ200-800 (Pg/mL)
‡ªµ¤Á o¤ oœ
(Pg/mL)
Áž°¦rÁŽÈœ˜r„µ¦¥´ ¥´ÊŠš¸ÉÁª¨µ 2 ª´œ (%)
1 2 Complex Cu-1
0 0 0 0
200 73.9 0 13.6
400 79.5 0 26.1
800 90.9 0 44.3