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˜µ¦µŠš¸É 2 —Š o°¤¼¨Ÿ¨¹ „
¼˜¦Ã¤Á¨„» ¨ C67H98Cu3N10O23
œÊÎ µ®œ´„äÁ¨„»¨ (amu) 1602.1
°»–®£¼¤· (Á‡¨ª·œ) 293(2)K
‡ªµ¤¥µª‡¨ºÉœ 0.71073 Å
¦³Ÿ¨¹„ monoclinic
®¤¼n ž¦·£¼¤· C2/c
a 38.987(3) Å
b 12.3778(9) Å
c 29.748(2) Å
E 97.961(2)°
V (Å 3 ) 14217.2(18)
Z 8
Density (calculated) 1.497 Mg/m 3
Absorption coefficient 0.974 mm -1
F(000) 6728
Crystal size 0.325 x 0.179 x 0.077 mm 3
Final R indices [I>2sigma(I)] R1 = 0.0492, wR2 = 0.1444
R indices (all data) R1 = 0.0618, wR2 = 0.1567
„µ¦«¹„¬µ„µ¦Áž¨¸É¥œÂž¨Š °ŠÂ™„µ¦—¼—„¨ºœ FT-IR
‹µ„„µ¦«¹ „¬µ„µ¦—¼—„¨ºœÂŠ °Šµ¦¡ªnµ š¸ÉÁ¨ ‡¨ºÉœ 3413 cm-1 ¤¸„µ¦—¼ —„¨ºœÂŠ °ŠÃ¤Á¨„» ¨
œÊÎ µž¦µ„’°¥¼n š¸ÉÁ¨ ‡¨ºÉœ 1629 cm-1 ¤¸„µ¦—¼—„¨ºœÂŠ °Š®¤¼n C=O Ž¹ÉŠÁž}œ °Š¨·Â„œ—r ¢eœ· ¨°³¨µœ¸œ š¸ÉÁ¨ ‡¨ºÉœ
850 ¨³ 723 cm-1 ¤¸„µ¦—¼—„¨ºœÂŠ °Š®¤¼n C-H wag ¨³ C-H ring ˜µ¤¨Îµ—´ Ž¹ÉŠÁž}œ„µ¦—¼ —„¨ºœÂŠ °ŠªŠÁœ
Ž¸ œÄœÃ¤Á¨„»¨ °Š 1,10-¢eœœÃš¦¨¸œ —´ŠÂ—ŠÄœ˜µ¦µŠš¸É 3
˜µ¦µŠš¸É 3 —ŠÂ™„µ¦—¼—„¨ºœš¸É ε‡´ °Šµ¦ž¦³„°‡°žÁž°¦r„´¢eœ· ¨°³¨µœ¸œ ¨³ 1,10-¢eœœÃš¦¨¸œ
ž¦³Á£š„µ¦´Éœ/Á¨ ‡¨ºÉœ (cm-1)
O-H C=O N-H C-H sp3 C-H sp 2 C-H wag C-H ring
µ¦ž¦³„° 3413 1629 3286 2929 3051 850 723
°o µŠ°·Š‹µ„ H. Laila ¨³‡–³ (1995)