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„µ¦«¹„¬µ„µ¦Áž¨¸É¥œÂž¨Š¦³®ªnµŠ°»–®£¼¤·„´ „µ¦¼Á¸¥œÊ宜´„—o ª¥ TGA
„µ¦¼ Á¸¥œÊ宜´„š¸ÉnªŠ°»–®£¼¤·¦³®ªnµŠ 50 oC ™¹Š 1,000 oC ¡ªnµ¤¸„µ¦¼Á¸¥œÊÎ µ®œ´„ 5 nªŠ°»–®£¼¤·
—oª¥„´œ —´ Šœ¸Ê nªŠš¸É 1 °» –®£¼¤· 49 oC – 135 oC ‹³¼Á¸¥Ã¤Á¨„»¨ °ŠœÊε nªŠš¸É 2 nªŠ°»–®£¼¤· 135 oC – 154 oC ‹³
¼Á¸¥®¤¼nÁœŽ·œ °Š¢eœ· ¨°³¨µœ¸œ nªŠš¸É 3 nªŠ°»–®£¼¤· 154 oC – 232 oC ‹³¼Á¸¥®¤¼n ‡µ¦r°œ·¨ n ªŠš¸É 4 nªŠ
°»–®£¼¤· 232 oC – 321 oC ‹³¼Á¸¥®¤¼n°³¤·Ãœ ¨³nªŠš¸É 5 nªŠ°»–®£¼¤· 321 oC – 464 oC ¨³ 464 oC - 750 oC ‹³
¼Á¸¥ äÁ¨„»¨ °Š 1,10-¢eœœÃš¦¨¸œ —´ŠÂ—ŠÄœ˜µ¦µŠš¸É 4
˜µ¦µŠš¸É 4 —Š o°¤¼ ¨„µ¦¼Á¸¥œÊÎ µ®œ´„ °Š˜´ª°¥n µŠš¸É°»–®£¼¤·˜nµŠÇ °Šµ¦ž¦³„°‡°žÁž°¦r„´¢e
œ·¨°³¨µœ¸œ ¨³ 1,10-¢eœœÃš¦¨¸œ
µ¦ž¦³„°
®¤¼n¢{ Š„r´œ/°» –®£¼¤· (oC)
H2O
phenylalanine
1,10 - phenanthroline
C6H6 CO NH
µ¦ž¦³„° 49 – 135 135 – 154 154 – 232 232 – 321 321 – 464, 464 – 750
°oµŠ°·Š‹µ„ E. Ramachandran (2007) ¨³ R. P. Sharma (2009)
„µ¦«¹„¬µ‡nµ„µ¦—¼—„¨ºœÂŠ °Šµ¦ž¦³„°Ã—¥Á‡¦ºÉ°Š¥¼ª¸-ª· ·Á·¨
‹µ„„µ¦«¹„¬µ¨´„¬–³„µ¦—¼—„¨ºœÂŠ¡ªnµš¸É‡ªµ¤¥µª‡¨ºÉœ 273 ¨³ 295 œµÃœÁ¤˜¦ Áž}œ„µ¦—¼ —„¨ºœÂŠ
Ĝ¨´„¬–³ ʌ - ʌ* ¨³ n – ʌ*°ŠªŠÁœŽ¸œÄœ¨·Â„œ—r ¨³š¸É‡ªµ¤¥µª‡¨ºÉœ 629 œµÃœÁ¤˜¦Áž}œ„µ¦—¼ —„¨ºœÂŠÄœ
¨´„¬–³ °Š d-d š¦µœŽ·´œš¸É¤¸„µ¦™nµ¥Áš°·Á¨È„˜¦°œ‹µ„¨·Â„œ—rŞ¥´ŠÃ¨®³
¦»žŸ¨„µ¦š—¨°Š
„µ¦´ŠÁ‡¦µ³®r µ¦ž¦³„°Á·ŠŽo °œš°ŠÂ—Š„´ ¢e œ·¨°³¨µœ¸ œÂ¨³ 1,10-¢eœœÃš¦¨¸œ—o ª¥ª·›¸ „µ¦
´ŠÁ‡¦µ³®r š¸É °»–®£¼ ¤· ®o °Š ץčoš°ŠÂ—Š „´¢e œ· ¨°³¨µœ¸œÂ¨³ 1,10-¢e œœÃš¦¨¸ œÁž} œµ¦˜´ÊŠ˜oœ µ¦š¸É
´ŠÁ‡¦µ³®r ŗo¤¸ ¼˜¦—´Šœ¸Ê [Cu3(phen)4(phe)2CO3]˜15H2O ¤¸¨´„¬–³Áž} œÂÅ˜¦œ·ªÁ‡¨¸¥¦r ‹µ„œ´ÊœœÎ µÅž®µ®¤¼n
¢{ Š„r ´œ °Šµ¦ž¦³„°œ¸Ê Á¡ºÉ°¥ºœ¥´œ°Š‡rž¦³„° ¡ªnµ š¸É Á¨ ‡¨ºÉœ 3413 cm -1 ¤¸®¤¼n¢{Š„r ´œÅ±—¦°„Ž¸°Š
äÁ¨„»¨œÊ垦µ„’°¥¼n Á¨ ‡¨ºÉœ 1629 cm -1 ¤¸®¤¼n ¢{Š„r´Éœ C=O Ž¹ÉŠÁž}œ °Š¢eœ·¨°³¨µœ¸ œ Á¨ ‡¨ºÉœ 850 ¨³ 723 cm-1
¤¸®¤¼n¢{ Š„r´Éœ C-H wag ¨³ C-H ring ˜µ¤¨Îµ—´ Ž¹ÉŠÁž}œ 1,10-¢eœœÃš¦¨¸ œ Á¤ºÉ°ª·Á‡¦µ³®r „µ¦¼Á¸¥œÊÎ µ®œ´„
š¸ÉnªŠ°»–®£¼¤·¦³®ªn µŠ 50 oC ™¹ Š 1,000 oC ¡ªnµ¤¸„µ¦¼Á¸¥œÊÎ µ®œ´„ 5 nªŠ°»–®£¼¤·—oª¥„´œ —´ Šœ¸Ê nªŠš¸É 1 °»–®£¼¤·
49 oC – 135 oC ‹³¼Á¸¥œÊε °ŠÅ±Á—¦˜ nªŠš¸É 2 nªŠ°»–®£¼¤· 135 oC – 154 oC ‹³¼Á¸¥®¤¼nÁœŽ· œ nªŠš¸É 3 nªŠ
°»–®£¼¤· 154 oC – 232 oC ‹³¼Á¸¥®¤¼n ‡µ¦r°œ· ¨ nªŠš¸É 4 nªŠ°»–®£¼¤· 232 oC – 321 oC ‹³¼Á¸¥®¤¼n °³¤·Ãœ
¨³nªŠš¸É 5 nªŠ°»–®£¼¤· 321 oC – 464 oC ¨³ 464 o C - 750 oC ‹³¼Á¸¥ äÁ¨„»¨ °Š 1,10-¢eœœÃš¦¨¸œ
¨³‹µ„„µ¦«¹„¬µ‡nµ„µ¦—¼ —„¨ºœÂŠ °Šµ¦ž¦³„°Á·ŠŽo °œœ¸Ê¡ªn µ‡nµ„µ¦—¼—„¨º œ¼Š»—¤¸‡nµÁšn µ„´ 629 nm
‡nµ Absorbance Ášnµ„´ 0.252 Ž¹ÉŠÁž}œ„µ¦—¼ —„¨ºœÄœ¨´„¬–³ °Š d-d transition nªœš¸É‡ªµ¤¥µª‡¨ºÉœ 295, 273, 225
nm Áž}œ„µ¦—¼—„¨ºœÂŠÄœ¨´„¬–³ charge-transfer complex °Š®¤¼n¢{ Š„r´œ °Š¨· „œ—r