1106
êćøćÜìĊę
1
ך
ĂöĎ
úñúċ
Ö×ĂÜÿćøðøąÖĂï [Cu(Hsal)(phen)]
2
(H
2
O)
2
(Hsal)(CH
3
COOH)
óćøćöĉ
đêĂøŤ
ך
ĂöĎ
ú
Empirical formula
C
47
H
40
Cu
2
N
4
O
13
Temperature
296(2) K
Wavelength
0.71073 Å
Formula weight
995.91
Crystal system
Triclinic
Space group
1 ǰ
Unit cell dimensions
B
= 12.0010(19) Å
ߙ
= 93.111(5)°
C
= 12.061(2) Å
ߚ
= 108.557(5)°
D
= 16.222(2) Å
ߛ
= 106.642(5)°
Volume
2105.1(6) Å 3
;ǰ
2
Density (calculated)
1.571 mg/m 3
Crystal size
0.44 x 0.16 x 0.11 mm 3
Goodness-of-fit on
'
2
1.024
Final
3
indices [I>2
ı
> (I)]
3
= 0.0479, w
3
= 0.1225
3
indices (all data)
3
= 0.0713, w
3
= 0.1389
ñúÖćøýċ
ÖþćĀöĎŠ
ôŦ
ÜÖŤ
ßĆ
î×ĂÜÿćøéš
ü÷ĒÿÜĂĉ
îôćđøé
ÿđðÖêøĆ
öĒÿéÜÿĆ
ââćèĀöĎŠ
ôŦ
ÜÖŤ
ßĆ
î×ĂÜÿćøðøąÖĂï [Cu(Hsal)(phen)]
2
(H
2
O)
2
(Hsal)(CH
3
COOH) éĆ
ÜõćóìĊę
3
óïÿĆ
ââćèÖćø÷Č
é×ĂÜ Cu-O ìĊę
đú×ÙúČę
îðøąöćè 534 cm
-1
[7] ÿĆ
ââćèÖćø÷Č
é×ĂÜǰO-H ×ĂÜ H
2
O ìĊę
đú×ÙúČę
îǰ3,392
cm
-1
ÿĆ
ââćèÖćø÷Č
é×ĂÜǰC=O ĒïïĂÿööćêø (asymmetric) Ēúąÿööćêø (symmetric) ×ĂÜĀöĎŠ
COO
-
×ĂÜǰHsal ìĊę
đú×ÙúČę
î 1,628 Ēúąǰ1,446 1,383 cm
-1
êćöúĞ
ćéĆ
ïǰÿĆ
ââćèÖćø÷Č
é×ĂÜ C=C ìĊę
đú×ÙúČę
îǰ1,582 cm
-1
, C=N ìĊę
đú×ÙúČę
î
1,520 cm
-1
×ĂÜĀöĎŠ
ǰphen ĒúąÿĆ
ââćèÖćø÷Č
é×ĂÜ Cu(O)-C ìĊę
đú×ÙúČę
îǰ1,250 cm
-1
[6,8]
õćóìĊę
ǰ3
ÿđðÖêøĆ
öÿĆ
ââćèĀöĎŠ
ôŦ
ÜÖŤ
ßĆ
î×ĂÜÿćøðøąÖĂïǰ[Cu(Hsal)(phen)]
2
(H
2
O)
2
(Hsal)(CH
3
COOH)
